The reason for a slight increase in FF and V oc is also mirrored from the EIS result here. Figure 5 Electrochemical impedance and Raman spectra of HBH solar cells and film. Electrochemical impedance spectrum of CdTe NT/CdSe QD HBH solar cells (a) and Raman spectrum of NT/QD HBH film (b). The insert in (b) shows the enlarged signals from 150 to 220 cm-1. Raman spectrum is a useful tool as it provides short-ranged microstructure information that is further helpful to understand the electric behavior in the EIS result. As shown in Figure  5b, compared

with the OA-capped HBH film, Quizartinib research buy both the first and the second longitudinal optical phonon mode of CdTe can be observed around 165 cm-1 (1LO1) and 330 cm-1 (2LO1) after the NT/QD HBH film was treated with MPA (sample B). The same phenomenon happens with CdSe. The enhancement in Raman peak intensity was suggested to be correlated with molecule adsorption (with large polarity such as GW786034 this) that induced the passivation of surface states [20–22]; herein, there was an adsorption of MPA on the surface of CdTe NTs and CdSe QDs through Cd-S bond which reduces the electron SHP099 supplier trapping state caused by the Cd dangling bond.

This correspondingly results in a decreased charge trapping and recombination rate, as exhibited from the EIS analysis in Figure  5a. Interestingly, a slight blueshift of the 1LO1 mode from CdTe and 1LO2 mode from CdSe can be observed after MPA treatment, which, in accordance with TEM characterization in Figure  3, indicates a more densely packed microstructure in the hybrid film [23]. Figure  6 shows the J sc and E ff dependence on the mass ratio of CdTe NTs to CdSe QDs. The maximum J sc is found to be at an optimum ratio of 2:1, beyond which the J sc value drastically

decreases due to a relative lack of photoactive CdTe. The variation of E ff is mainly dominated by J sc, reaching a remarkable value of 0.53% at 2:1. Note that this optimum mass ratio is much Plasmin larger than that in the research with both spherical-shaped nanoparticles [9]. It is easily understandable that the mass of one CdTe nanotetrapod is several times larger than that of one CdSe quantum dot; the optimized CdTe/CdSe ratio ensures a suitable quantity of CdSe QDs surrounding one CdTe nanotetrapod so that a continuous percolation of both CdTe and CdSe is achieved. In this way, efficient charge extraction is allowed by virtue of the interpenetrated donor-acceptor networks. Figure 6 The effect of CdTe NT/CdSe QD mass ratio on HBH solar cell characteristics. In order to evaluate the NT/QD hybrids in facilitating the device’s energy conversion efficiency, a direct comparison of EQE and light absorption of solar cells was carried out, and the result is shown in Figure  7.